Mulberry & Vine New York City

Coordination of the [2]pseudorotaxane to silver(I) was observed through 1H NMR spectroscopy, but a shift in equilibrium occurs as pseudorotaxane formation becomes less favourable. Chapter 5 describes the synthesis of a [3]rotaxane and the resulting coordination of the neutral [3]rotaxane ligand to a range of metals. Coordination to the metal center does occur but in […]